GG3068:  Atmospheric Pollution

LECTURE 4: Air Pollution in the home and workplace

 

 
 
 
 
 
 
 
 
 

Introduction


Control of air pollution has concentrated on major emission sources, such as industrial plants, power stations, traffic exhausts, etc. However, toxic substances only produce health problems when they reach the body, and thus the effects of pollutants depend on a combination of concentrations and human activity patterns. There has been a recent shift in focus in pollution monitoring, especially by US Environmental Protection Agency (EPA), which looks at patterns of human exposure to pollutants. This approach has been permitted by the development of instruments small enough be worn on the body, and sophisticated enough to detect levels of wide range of harmful substances. Studies of more than 3,000 subjects in 14 US states and 1 Canadian province tracked human exposure to 30 different Volatile Organic Compounds (VOCs: hydrocarbons), PM10 (respirable particulates), pesticides, and carbon monoxide. These studies strikingly showed that the highest levels of human exposure occur indoors, not outdoors. The implications of this work are profound: by focusing on which pollutant sources coincide with the most serious exposure, esources can be targeted much more efficiently on tacking pollution threats to human health.
 
 

Emissions and exposure


Most people in developed countries spend much of their time indoors: working, relaxing, eating, sleeping, so it is levels of pollution in indoor environments that are most relevant to exposure levels. Exposure levels may be very different from what would be expected from highest emission sources.
 

Benzine: an example.

Benzine is a VOC present in petrol, some household products, and cigarette smoke. Benzine is carcinogenic: known to cause cancer in workers continually exposed to high concentrations.  Most benzine released into environment in US is from vehicle exhausts (82%), with lesser amounts contributed by industrial souces (14%), individual activities (use of glues, paints, etc.: 3%); and only 0.1% from tobacco. However, average amounts of human exposure are very different: only 18% of exposure is due to vehicle exhausts and 3% from industrial sources; but 34% from individual activities and 45% from cigarettes. Note that these are average figures, and proportions will clearly vary with occupation and range of activities, but the difference between total emissions and personal exposure are very striking.
 
 

Air pollution in the workplace


Pollution associated with industrialisation has had severe effects on workers in factories, where levels of pollutants may be very high. In the 19th C., air quality was very low in many types of factory, from gases and airborne particulates. The health problems associated with certain trades were well known. For example, Lewis Carroll’s Mad Hatter was a charicature of brain-damaged milliners who were regularly exposed to mercury vapours (the American equivalent to the phrase ‘Mad as a hatter’ was ‘the Danbury Shakes’, after the American centre of the hat industry).

Problems associated with particulates were especially severe, with high levels in many workplaces. In the 19th C., cotton mills had high levels of lint particles in air, leading to lung disease (byssinosis). Particulates severely affected cutlery grinders and miners in particular.

Case study I: coal mining
Coal mining has long been associated with serious hazards and health risks, including explosions, fires and tunnel collapses. There are two main air quality hazards: coal gas, and particulates. Coal gas is toxic and highly flammable. The traditional 'miner's canary' was taken unbderground to warn of coal gas hazards. When the canary died, it was time to get out. Coal miners have long suffered health problems due to the inhalation of fine coal dust particles, which lodge in the lung. Two principal diseases are common among miners: emphysema and chronic bronchitis. Emphysema is a lung disease involving damage to the air sacs or alveoli. The lungs lose their elasticity and become less able to expand and contract. The alveoli cannot deflate completely so less oxygen is taken into the lungs, leading to breathing difficulties. Cigarette smoking is the most frequent cause of emphysema but for the miners it was the coal dust which was held to be mainly responsible for the disease. Chronic bronchitis is an inflammation of the bronchi, the main air passages to the lungs. It occurs over a long period and recurs over several years. The severity of the disease relates to the amount and duration of the exposure to coal dust and to a great extent whether the sufferer smokes cigarettes.

Compensation claims are proceeding against coal mining companies in Europe and North America. In the UK, the High Court awarded six miners up to £10,000 each in January 1998 for pain, suffering and disability from emphysema and chronic bronchitis. All but one of the claims were reduced because smoking contributed to the diseases, but the test case opened up the way for further action by 93,000 other miners.

Case study II: asbestos
Health problems due to various uses of asbestos have also become obvious during recent decades. Asbestos refers to a group of minerals that occur naturally as masses of strong, flexible fibres that can be separated into thin threads and woven, or compressed into slabs. Four main types were used: chrysotile, amosite, crocidolite (blue asbestos), and anthophyllite. Asbestos is not flammable, is inert, and do not conduct electricity. For these reasons, asbestos has been widely used in many industries and products, including:
 

Asbestos fibre masses tend to break easily into a dust composed of tiny particles that can float in the air and stick to clothes. They may be swallowed, or if the fibres are small enough, they may be inhaled deep into the lungs causing serious health problems. Most of the problems were suffered by workers who handled asbestos materials, for example asbestos mining and milling; manufacture (e.g. shipbuilding, textiles and other asbestos products) construction work, brake repair, demolition workers, and firefighters, mainly in the three decades during and after World War II. By the 1970s, the health problems were becoming well known, bringing about legislation and a dramatic reduction it its use. The main health effects are:
Generally, workers who develop asbestos-related diseases show no signs of illness until many years after first exposure. For example, the time between first
exposure to asbestos and the appearance of lung cancer is generally 15 years or more; a lag of 30 to 35 years is not unusual. The lag period for development of
mesothelioma and asbestosis is even greater, often as long as 40 to 45 years.

Many studies have shown that the combination of smoking and asbestos exposure is particularly hazardous. Cigarette smokers, on the average, are 10 times as
likely to develop lung cancer as are nonsmokers. For nonsmokers who work with asbestos, the risk is about five times greater than for those in the general
population. By contrast, smokers who also are heavily exposed to asbestos are as much as 90 times more likely to develop lung cancer than are nonexposed
individuals who do not smoke. Smoking does not appear to increase the risk of mesothelioma, however.

Many buildings still contain asbestos insulating materials, and the removal of such materials has to be done under very stringent conditions: was done in the Irvine Building (February 2000).

Case Study 3: Bhopal

Bhopal, India: Union Carbide Corporation pesticide plant producing Methyl Isocyanate (MC) began production in 1979.

On December 2, 1984,  during routine maintenance, a large quantity of water entered storage tank. This caused a runaway reaction, in which temperature and pressure increased, and burst a tank, allowing MC gas to escape at 12.30 a.m. Cloud of heavy, poisonous gas enveloped the sleeping town, especially the shanty areas nearest the plant.

Safety systems were inadequate, and no warning was given to the communities in Bhopal until 1 hour after the leak.

According to government figures:
c. 3,800 people died,
40 experienced permanent total disability, and
2,680 persons permanent partial disability.

1989: Supreme Court of India directed Union Carbide Corporation (UCC) and UCIL to pay a total of $470 million

This money ws paid, but there are persistent claims that money did not reach the poorest people, i.e. those most affected. The number and conditions of victims is also contentious, some claiming that the death toll is still rising, others (i.e. Union Carbide) that there is no longer any problem.

This case study raises several important issues:
are safety standards less in the developing world?
do corporations meet their responsibilities there, as they would be expected to in the west?

Victim support:
http://www.ucaqld.com.au/community/bhopal/
explain.html

Union Carbide story:
http://www.bhopal.com/

Good overview and reference list:
http://www.american.edu/TED/BHOPAL.HTM
 
 

Conditions in workplaces have improved in developed world in recent decades, due to the introduction of comprehensive health and safety laws. However, serious problems persist in 3rd world where legislation is less stringent. Also, new hazards are continuously being identified, and workers do not always choose to follow health advice. The modern office presents many potential hazards in the form of solvents released from felt pens, toner, correction fluid and inks. Levels of VOCs may be high in stationery cupboards, and by photocopiers in poorly ventilated rooms.
 

Air pollution: home and recreation
 

Smoking:

Of all air pollutants to which humans are commonly exposed, tobacco smoke poses the greatest health risk. This refers both to active smokers and and passive smoking. High CO levels impair respiratory efficiency; but it is the coctail of other compounds that pose the greatest health risks. Tobacco smoke contains a wide variety of toxic compounds, many of which cause lung cancers and other respiratory diseases. Comparison of tobacco smoke with outdoor pollutants is very revealing: in an average room, a single cigarette can cause aerosol concentrations of 2000 migrogrammes per cubic metre, and are much higher still in the smoke directly inhaled from the cigarette. Risks have led to smoking bans in many public buildings.

Cooking and heating: an old problem, probably dating back to the use of fire. Smoky fires produce soot particles and carbon monoxide (C0) produced by incomplete combustion. Old or poorly maintained gas cookers, heaters and boilers can be serious source of CO. Combustion also releases sulphur and nitrogen oxides into homes.
 
Solvents, paints, building materials (particle board, chipboard, plywood: bonded with resins, important source of VOCs in the home). Building and decorating materials may leak toxic compounds into rooms for considerable periods.

Dry-cleaned clothes: concentrations can be high in wardrobes where newly-cleaned clothes are stored. Can even cause death: case of child who died while sleeping in a dry-cleaned sleeping bag.

Carpets: New carpets can be a major source of VOCs; US EPA has entered into negotiations with carpet manufacturers to reduce levels. Carpets (esp. deep pile) are also reservoirs for toxic chemicals (e.g. insecticides such as DDT) and fine particulates. Contribute substantially to exposure of young children, who play on floors, crawl around on carpets, and regularly put their hands in their mouths. Personal clouds created by disurbance of fine particulates from reservoirs such as carpets and furniture by movement of people, so that the exposure of a moving person is much higher than recorded by a stationary instrument.
 

Radon


Radon is a naturally occurring radioactive gas, produced by decay of uranium. Uranium is commonly found in granites, so it varies in natural concentration according to geology. Radon is an unstable element, and decays through a series of daughter products (isotopes of polonium, Lead, and Bismuth), each of which releases either alpha or beta radiation (high velocity helium nucleii or electrons, respectively). The daughters are short-lived (seconds to days), but can be inhaled on dust, so radio decay releases radiation directly into the lungs. Radon and daughters accumulate in poorly ventilated homes following outgassing from rocks and soil, building stone, or well water. In tightly-sealed, insulated homes in radon areas, concentrations may be ‘00s or ‘000s times those outside. Overall, radon contributes about half of total radiation exposure of public. Radon constitutes a health risk by increasing levels of ionizing radiation, which may lead to lung cancer. Risk established by studies of uranium mine workers, who suffer elevated levels of lung cancer.  EPA estimates that radon is responsible for 5,000 to 20,000 cancer deaths annually.

Sick Buildings


Health effects associated with known or suspected airborne pollutants. Building-related illness: May appear after single, high dose exposure or repeated exposures: irritation of eyes, nose and throat, headaches, dizziness, fatigue, triggering of athsma attacks. Treatment may simply consist of removing person’s exposure to pollutant, if it can be identified, or improving ventilation. Longer-term problems: cancers, heart problems and liver damage.
Sick-building syndrome: sometimes building occupants experience symptoms which do not fit the pattern of any known illness and are hard to trace to specific sources. However, distinction between SBS and BRI is blurring as more causes are identified. Effects may be temporary or long term.
Sharp drop in indoor air quality when building ventilation was cut in 1970s in attempt to conserve energy. Poor ventilation allows concentrations to rise (e.g. around photocopier or in stationary cupboard).
Buildings related illnesses may be due to building materials, or unsuitable operation, maintainance or ventilation of buildings. Problems may be due in part to non-pollutant stressors: temperature, humidity, lighting, electromagnetic fields, or social/psychological stresses. Multiple Chemical Sensitivity
BRI and SBS both incur large costs. Implicated by EPA as cause of up to 5,000 cancers per year in US. Costs to economy: estimated $60 billion in medical costs, loss of time from work, decreased work efficiency.
Remedies:
Improved ventilation. Ventilation promotes removal of pollutants, stopping indoor air quality from reaching dangerous levels.
Use of plants to break down pollutants. Azaleas, rubber plants and poinsettias tackle formaldehyde; lilies break down acetone, benzine.
Replacement of source materials. eliminating the sources of indoor pollution requires adoption of greener technology: building materials, paints, varnishes, etc. Such alternatives are available, but are currently expensive and difficult to obtain.
 

References:

Ott, W.R. and Roberts, J.W. 1998: Everyday exposure to toxic pollutants. Scientific American, February, 72-77.

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