Prof Sharon E. Ashbrook
Deputy Head of School
Professor
Biography
Professor Ashbrook studied for an MChem Chemistry degree at Hertford College, University of Oxford, before completing her DPhil, also at Oxford in the Physical and Theoretical Chemistry Laboratory, under the supervision of Stephen Wimperis. After a postdoc at the Unviersity of Exeter, Professor Ashbrook was awarded a Royal Society Dorothy Hodgkin Fellowship, which she held in the Department of Earth Sciences at the University of Cambridge. During this time she also held the Charles and Katherine Darwin Research Fellowship at Darwin College. Professor Ashbrook moved to St Andrews in 2005, when she was awarded an RCUK Academic Fellowship, and was promoted to Reader in 2009 and Professor in 2013. She was awarded a Royal Society Wolfson Merit Award in 2015, and elected FRSE in 2016. She has also been awarded the RSE Makdougall Brisbane Medal (2012) and the RSC Harrison Prize (2004), Marlow Award (2011), Corday Morgan Award (2015) and Bourke-Liversidge Award (2021). In 2017, she was awarded a Suffrage Science Award. Professor Ashbrook also acts as the Professorial Senate Assessor for Science and Medicine on University Court.
Teaching
CH1301 The Impact of Chemistry (5 lectures and module convenor)
CH1401 Introductory Inorganic and Physical Chemistry (tutorials)
CH1402 Inorganic and Physical Chemistry 1 (tutorials)
CH2701 Physical Chemistry 2 (14 lectures, 6 tutorials and laboratory)
CH3431 Chemistry workshop (10 workshops)
CH4717 Fundamentals of Spectroscopy of Molecules and Solids (9 lectures and 1 laboratory)
CH444/CH5441 Honours Project Assessment
Research areas
Our research aims to combine high-resolution multinuclear Nuclear Magnetic Resonance (NMR) spectroscopy with periodic first-principles calculations to investigate structure, order and dynamics in the solid state. Research involves the development of new experiments, implementation and improvement of existing experiments and the application to systems of interest in chemistry, geology and materials science. Particular emphasis is given to nuclei which possess a nuclear electric quadrupole moment, such as 17-O, 23-Na or 27-Al, which account for over 75% of all NMR-accessible nuclides. Current areas of interest include high-pressure minerals, microporous framework materials and ceramic materials proposed for the encapsulation of nuclear waste.
For more information see the SEA group website: http://chemistry.st-andrews.ac.uk/staff/sa/group/Site/Home.html
PhD supervision
- Heitor Secco Seleghini
- Sharminaz Chollampattu Sageer
- Jonathan Keys
- Deborah Brako-Amoafo
- Malavika Manoj
- Daniela Almeida Vieira Fogaca Da Rocha
- Yinxuan Zhang
- Marek Karpíšek
Selected publications
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Open access
A picture of disorder in hydrous wadsleyite – under the combined microscope of solid-state NMR spectroscopy and ab initio random structure searching
McKay, D., Moran, R. F., Dawson, D. M., Griffin, J. M., Sturniolo, S., Pickard, C. J., Berry, A. J. & Ashbrook, S. E., 20 Feb 2019, In: Journal of the American Chemical Society. 141, 7, p. 3024–3036 13 p.Research output: Contribution to journal › Article › peer-review
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Open access
Hydrolytic stability in hemilabile metal–organic frameworks
McHugh, L. N., McPherson, M. J., McCormick, L. J., Morris, S. A., Wheatley, P. S., Teat, S. J., McKay, D., Dawson, D. M., Sansome, C. E. F., Ashbrook, S. E., Stone, C. A., Smith, M. W. & Morris, R. E., Nov 2018, In: Nature Chemistry. 10, 11, p. 1096–1102 7 p.Research output: Contribution to journal › Article › peer-review
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Open access
Perspective: current advances in solid-state NMR spectroscopy
Ashbrook, S. E. & Hodgkinson, P., 28 Jul 2018, In: Journal of Chemical Physics. 149, 4, 040901.Research output: Contribution to journal › Review article › peer-review
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Open access
17O solid-state NMR spectroscopy of A2B2O7 oxides: quantitative isotopic enrichment and spectral acquisition?
Fernandes, A., Moran, R., Sneddon, S., Dawson, D. M., McKay, D., Bignami, G. P. M., Blanc, F., Whittle, K. & Ashbrook, S. E., 14 Feb 2018, (E-pub ahead of print) In: RSC Advances. 8, 13, p. 7089-7101Research output: Contribution to journal › Article › peer-review
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Open access
Cost-effective 17O enrichment and NMR spectroscopy of mixed-metal terephthalate metal-organic frameworks
Bignami, G. P. M., Davis, Z. H., Dawson, D. M., Morris, S. A., Russell, S. E., McKay, D., Parke, R. E., Iuga, D., Morris, R. E. & Ashbrook, S. E., 28 Jan 2018, In: Chemical Science. 9, 4, p. 850-859Research output: Contribution to journal › Article › peer-review
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Open access
The effects of extraframework species on the structure-based prediction of 31P isotropic chemical shifts of aluminophosphates
Dawson, D. M., Seymour, V. R. & Ashbrook, S. E., 21 Dec 2017, In: Journal of Physical Chemistry C. 121, 50, p. 28065-28076Research output: Contribution to journal › Article › peer-review
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Open access
In situ solid-state NMR and XRD studies of the ADOR process and the unusual structure of zeolite IPC-6
Morris, S. A., Bignami, G. P. M., Tian, Y., Navarro-Rojas, M., Firth, D. S., Cejka, J., Wheatley, P. S., Dawson, D. M., Slawinski, W. A., Wragg, D. S., Morris, R. E. & Ashbrook, S. E., Oct 2017, In: Nature Chemistry. 9, 10, p. 1012-1018 7 p.Research output: Contribution to journal › Article › peer-review
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Open access
Calculation and experimental measurement of paramagnetic NMR parameters of phenolic oximate Cu(II) complexes
Dawson, D. M., Ke, Z., Mack, F. M., Doyle, R., Bignami, G. P. M., Smellie, I. A., Buehl, M. & Ashbrook, S. E., 28 Sept 2017, In: Chemical Communications. 53, 76, p. 10512-10515Research output: Contribution to journal › Article › peer-review
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Open access
Synthesis, isotopic enrichment and solid-state NMR characterization of zeolites derived from the assembly, disassembly, organisation, reassembly process
Bignami, G. P. M., Dawson, D. M., Seymour, V. R., Wheatley, P. S., Morris, R. E. & Ashbrook, S. E., 12 Apr 2017, In: Journal of the American Chemical Society. 139, 14, p. 5140-5148 9 p.Research output: Contribution to journal › Article › peer-review