Prof Neville V Richardson
Emeritus Professor
Research areas
The Chemistry of Molecules at Surfaces. *Understanding the fundamental aspects of the interactions of molecules with surfaces underpins many advanced technologies, such as molecular electronics, optoelectronics, sensors, heterogeneous catalysis, displays, functional coatings etc. It is a challenge to the surface scientist to unravel the intricacies of these interactions and to design novel systems to exploit molecular and surface properties to advantage. *Multifunctional molecules at surfaces display a rich and varied chemisorption behaviour. On the one hand, bonding to semiconductor surfaces tends to be dominated by strong covalent interactions, limited adsorbate diffusion and structures which are relatively insensitive to coverage and temperature. On the other hand, on metal surfaces where diffusion is relatively uninhibited a subtle balance between interadsorbate, lateral interactions and adsorbate-substrate bonding determines the molecular orientation, the two-dimensional crystallinity and in turn the electronic properties and reactivity.*Our current work is focused in the following areas:Organic molecules at silicon surfaces; Amino acids at metal surfaces; Polyaromatics and macrocylic molecules at metal and semiconductor surfaces; Alumina surfaces; The role of proteoglycans in surface biology; Carbon deposition on marine sediments
Selected publications
-
Open access
Adsorption of the prototypical organic corrosion inhibitor benzotriazole on the Cu(100) surface
Turano, M., Walker, M., Grillo, F., Gattinoni, C., Hunt, G., Kirkman, P., Richardson, N. V., Baddeley, C. J. & Costantini, G., Oct 2022, In: Corrosion Science. 207, 10 p., 110589.Research output: Contribution to journal › Article › peer-review
-
Open access
Copper adatoms mediated adsorption of benzotriazole on a gold substrate
Grillo, F., Gattinoni, C., Larrea, C. R., Lacovig, P. & Richardson, N. V., 30 Oct 2022, In: Applied Surface Science. 600, 154087.Research output: Contribution to journal › Article › peer-review
-
Open access
Surface confined hydrogenation of graphene nanoribbons
Sung, Y.-Y., Vejayan, H., Baddeley, C. J., Grillo, F., Richardson, N. V. & Schaub, R., 26 Jul 2022, In: ACS Nano. 16, 7, p. 10281–10291 11 p.Research output: Contribution to journal › Article › peer-review
-
Open access
Understanding the interaction of organic corrosion inhibitors with copper at the molecular scale: benzotriazole on Cu(110)
Turano, M., Walker, M., Grillo, F., Gattinoni, C., Edmondson, J., Adesida, O., Hunt, G., Kirkman, P., Richardson, N. V., Baddeley, C. J., Michaelides, A. & Costantini, G., 30 Dec 2021, In: Applied Surface Science. 570, 151206.Research output: Contribution to journal › Article › peer-review
-
Open access
Calculating the frequencies and intensities of strongly anharmonic modes of adsorbates on surfaces: a low-cost but accurate computational approach
Garrido Torres, J. A., Goetze, J. P., Grillo, F., Richardson, N. V., Früchtl, H. A., Hooley, C. A. & Schaub, R., 25 Jul 2019, In: Physical Review. B, Condensed matter and materials physics. 100, 3, 035433.Research output: Contribution to journal › Article › peer-review
-
Open access
On-surface condensation of low-dimensional benzotriazole–copper assemblies
Grillo, F., Batchelor, D., Larrea, C. R., Francis, S. M., Lacovig, P. & Richardson, N. V., 26 Jun 2019, (E-pub ahead of print) In: Nanoscale. In pressResearch output: Contribution to journal › Article › peer-review
-
Open access
Structure and reactivity of Cu-doped Au(111) surfaces
Grillo, F., Megginson, R., Christie, J., Francis, S. M., Richardson, N. V. & Baddeley, C. J., 19 May 2018, In: e-Journal of Surface Science and Nanotechnology. 16, p. 163-171Research output: Contribution to journal › Article › peer-review
-
Open access
Ethene to graphene: surface catalyzed chemical pathways, intermediates, and assembly
Wang, B., König, M., Bromley, C., Yoon, B., Treanor, M.-J., Garrido Torres, J. A., Caffio, M., Grillo, F., Fruchtl, H., Richardson, N. V., Esch, F., Heiz, U., Landman, U. & Schaub, R., 4 May 2017, In: Journal of Physical Chemistry C. 121, 17, p. 9413-9423 11 p.Research output: Contribution to journal › Article › peer-review
-
Open access
Biochemical and functional characterization of glycosaminoglycans released from degranulating rat peritoneal mast cells: insights into the physiological role of endogenous heparin
Lever, R., Smailbegovic, A., Riffo-Vasquez, Y., Gray, E., Hogwood, J., Francis, S. M., Richardson, N. V., Page, C. P. & Mulloy, B., Dec 2016, In: Pulmonary Pharmacology & Therapeutics. 41, p. 96-102 7 p.Research output: Contribution to journal › Article › peer-review
-
Open access
Regioselective bromination of 1,4-dimethoxy-2,3-dimethylbenzene and conversion into sulfur-functionalised benzoquinones
Aitken, R. A., Jethwa, S. J., Richardson, N. V. & Slawin, A. M. Z., 11 Mar 2016, In: Tetrahedron Letters. 57, 14, p. 1563-1566 4 p.Research output: Contribution to journal › Article › peer-review