Prof Christopher Baddeley

Head of School

Professor

Phone: +44 (0)1334 46 3804
Email: cjb14@st-andrews.ac.uk

Research areas

My research interests lie in the area of Surface Chemistry and its application to the understanding of heterogeneous catalysis. One strand of research focuses on the understanding of surface reaction mechanisms underpinning enantioselective heterogeneous catalytic reactions. Scanning tunnelling microscopy (STM) and surface vibrational spectroscopy (both reflection absorption infrared spectroscopy (RAIRS) and high resolution electron energy loss spectroscopy (HREELS)) are utilised in ultrahigh vacuum (UHV) to characterise the adsorption of chiral molecules onto metal surfaces and the interaction of pro-chiral reagents with chirally modified surfaces. Facilities are also available for STM and RAIRS measurements of adsorption processes at the liquid-solid interface – i.e. conditions more relevant to the real catalytic systems. Recently, research has focussed on strategies for the development of novel enantioselective systems involving the construction of porous 2-D surface architectures utilising intermolecular H-bonding, metal organic co-ordination and surface confined covalent bond formation.

In addition, the technique of medium energy ion scattering (MEIS, Daresbury Laboratory) is used to characterise the depth dependent composition of bimetallic surfaces – in particular focusing on the influence of catalytically relevant gas phase species on surface composition. Recently, this work has been extended from single crystal bimetallic systems to bimetallic nanoparticles on oxide surfaces.

PhD supervision

Alexander Rossin
Jinchuan Chen
Ines Bertaso

Selected publications

Open access

Adsorption of the prototypical organic corrosion inhibitor benzotriazole on the Cu(100) surface
Turano, M., Walker, M., Grillo, F., Gattinoni, C., Hunt, G., Kirkman, P., Richardson, N. V., Baddeley, C. J. & Costantini, G., Oct 2022, In: Corrosion Science. 207, 10 p., 110589.
Research output: Contribution to journal › Article › peer-review
Open access

Highly ordered N-heterocyclic carbene monolayers on Cu(111)
Angove, E., Grillo, F., Fruchtl, H. A., Veinot, A. J., Singh, I., Horton, J. H., Crudden, C. M. & Baddeley, C. J., 24 Feb 2022, (E-pub ahead of print) In: The Journal of Physical Chemistry Letters. 13, 8, p. 2051-2056
Research output: Contribution to journal › Article › peer-review
Open access

Surface confined hydrogenation of graphene nanoribbons
Sung, Y-Y., Vejayan, H., Baddeley, C. J., Grillo, F., Richardson, N. V. & Schaub, R., 26 Jul 2022, In: ACS Nano. 16, 7, p. 10281–10291 11 p.
Research output: Contribution to journal › Article › peer-review
Open access

Thermal behaviour of Cu and Au nanoparticles grown on CeO₂ thin films
Megginson, R., Grillo, F., Francis, S. M., Paes, V. Z. C., Trombini, H., Grande, P. L., Rossall, A. K., van den Berg, J. A. & Baddeley, C. J., 28 Oct 2021, (E-pub ahead of print) In: Applied Surface Science. In press, 151656.
Research output: Contribution to journal › Article › peer-review
Open access

Understanding the interaction of organic corrosion inhibitors with copper at the molecular scale: benzotriazole on Cu(110)
Turano, M., Walker, M., Grillo, F., Gattinoni, C., Edmondson, J., Adesida, O., Hunt, G., Kirkman, P., Richardson, N. V., Baddeley, C. J., Michaelides, A. & Costantini, G., 30 Dec 2021, In: Applied Surface Science. 570, 151206.
Research output: Contribution to journal › Article › peer-review
Open access

N-heterocyclic carbenes reduce and functionalize copper oxide surfaces in one pot
Veinot, A., Al-Rashed, A., Padmos, J. D., Singh, I., Lee, D. S., Narouz, M. R., Lummis, P. A., Baddeley, C. J., Crudden, C. M. & Horton, J. H., 7 Aug 2020, (E-pub ahead of print) In: Chemistry - A European Journal. Early View
Research output: Contribution to journal › Article › peer-review
Open access

Phenylacetylene hydrogenation coupled with benzyl alcohol dehydrogenation over Cu/CeO₂: a consideration of Cu oxidation state
Pischetola, C., Francis, S. M., Grillo, F., Baddeley, C. J. & Cárdenas-Lizana, F., 13 Nov 2020, (E-pub ahead of print) In: Journal of Catalysis. In press
Research output: Contribution to journal › Article › peer-review
Open access

Oligomerization of proline catalyzed by Ni on a Au(111) surface
Seljamae-Green, R. T., Robinson, T., Fruchtl, H. A. & Baddeley, C. J., 18 Apr 2019, In: Journal of Physical Chemistry C. 123, 15, p. 9935-9943
Research output: Contribution to journal › Article › peer-review
Open access

Structural and electronic characterisation of Cu/Au(111) near-surface alloys
Grillo, F., Megginson, R., Batchelor, D., Muntwiler, M. & Baddeley, C. J., 18 Jun 2019, In: Japanese Journal of Applied Physics. 58, SI, 5 p., SIIB09.
Research output: Contribution to journal › Article › peer-review
Open access

Effect of the pH in the growth of benzotriazole model layers at realistic environmental conditions
Mirarco, A., Francis, S. M., Baddeley, C. J., Glisenti, A. & Grillo, F., 1 Oct 2018, In: Corrosion Science. 143, p. 107-115
Research output: Contribution to journal › Article › peer-review

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